Difference Between Vaporization and Evaporation


Introduction

In nature, vaporization and evaporation are 2 processes that frequently occur. The real causes of why we want to water our garden in the summer and why milk boils in a pot on the stove are evaporation and vaporization. In reality, evaporation is a form of vaporization that occurs in our environment. Therefore, evaporation occurs more often than other vaporization processes like boiling. Although these two terms seem to have comparable meanings, there are still significant variances between them. These two processes barely vary from one another on a molecular level. Both are happening at various temperatures and surfaces.

What is the Vaporisation process?

It transitions the element/compound from its liquid or solid phase to the equivalent gas phase. It is also termed the destruction of substances by intense heat. The process of using heat to change material from a liquid or solid form to a gaseous state is known as vaporization. It should be highlighted that there is no shift inside the chemical composition as a result of these shifts in the form of matter from one to the other.

Types of Vaporization

Evaporation

It is a phase change, or the occurrence of a phase of material below the critical temperature, from the liquid to the vapour phase.

Evaporation always takes place on the surface and happens at temperatures lower than the boiling point at a certain pressure. Consequently, water abruptly escapes and enters the atmosphere

Evaporation may be seen when drying garments on a roof.

Boiling

Evaporation is comparable to boiling. Boiling is the generation of vapour as high water bubbles beneath the surface of the liquid, just like when we maintain the water jar over high heat, it transforms into bubbles, and eventually, the steam leaves into the atmosphere. It is also referred to as the state transition from the liquid state to the gaseous state.

GRAN ,Boiling water, CC BY 3.0

Sublimation

We all know that when the ice melts, it first changes to liquid, and this liquid then transforms into steam. However, there is a method that turns solid materials straight into gaseous forms without first converting them to liquid. Sublimation is therefore the direct transformation of a solid into a gas phase.

Christopher from Salem,OR,USA, Dry Ice Sublimation,CC BY-SA 2.0

Factor affecting the speed of Vaporisation.

  • The amount of a vapourising substance in the air.

  • Air Rate of Flow – This is partially related to the concentration points mentioned previously. The quantity of the chemical in the atmosphere is much less likely to rise over time if "fresh" air (air that is not already filled with a drug or other substances) is continually flowing over the material, allowing for faster evaporation. This is the result of the boundary layer at the evaporation area reducing with flow velocity, which also reduces the diffusion distance in the stagnant layer.

  • Intermolecular Forces - The more energy required to evacuate a liquid is directly proportional to the strength of the forces holding the molecules together. The vaporisation enthalpy describes this.

  • Pressure - Evaporation happens more quickly when the surface is not exerting as much pressure to stop molecules from launching themselves.

  • The Substance's Temperature – The molecules' surface kinetic energy increases with increasing material temperature, which also accelerates the pace at which they evaporate.

Examples

  • Wet garments are dried up as a result of the vaporisation process, which is also used in the industry to recover salt from seawater.

  • Several industrial processes employ this method to separate the components of a mixture.

What is the Evaporation process?

The process of evaporation is the change from a liquid to a gas that takes place below the boiling point at the specified pressure. Additionally, it takes place on the surface rather than underneath, as in the vaporisation process. Evaporation is a sort of vaporisation process that transforms a liquid's surface into a gas.

Vidralta,Evaporation, CC BY 3.0

Difference between Vaporisation and Evaporation

Vaporisation Evaporation
It is described as a compound or element's boiling point change over phase. It is nothing more than a particular type of vaporisation that mostly takes place when the temperature is below boiling temperature.
By converting stuff from a liquid or solid to a gas, it alters its condition. It converts the substance's liquid condition immediately into a gas.
In most cases, it happens quickly and with little energy needed. In general, it takes longer and requires more energy.
All of the water transforms into a gas during the vaporisation process. Only the top layer of water turns into gases throughout evaporation.
Molecules may also emerge from below a liquid's surface during vaporisation. Only the molecules on the liquid's surface evaporate when a liquid is evaporating.

Conclusion

It can be concluded that evaporation is a kind of vaporisation in which the transition from a liquid to gas occurs in the region below the boiling point at a certain pressure. An element or compound transitions from a solid/ liquid state to a gaseous form through vaporisation. Vaporisation changes the phase or form of matter from a liquid or solid to a gaseous state, whereas evaporation transforms a liquid state of matter into a gas. Boiling, sublimation, or evaporation can all result in vaporisation, whereas the appropriate combination of heat, humidity, and airflow can cause evaporation.

FAQs

1. How do a liquid's vapour pressure and intermolecular forces relate to one another?

Liquid's vapour pressure is inversely correlated with its intermolecular forces, meaning that as intermolecular forces are stronger, it gets lower.

2. Describe why heating ice over its 0 °C temperature does not affect its temperature?

In response, heated ice absorbs energy. As a result, the intermolecular attractive forces dissipate, causing the solid to transition into a liquid state. The system's temperature stays at 0 °C until all of the water in it has frozen. Only when the volume of water increases to vanishing does the temperature of the water rise.

3. Describe why adding heat to boiling water at 100° C does not affect its temperature?

When heated, water takes energy. As a result, the intermolecular attractive interactions dissipate, causing the liquid to shift into a gaseous state. The system's temperature is maintained at 100 °C until the water has finished boiling. Only when the volume of liquid water increases till vanishing does the temperature of the water increase.

4. At 100°C, water vapour burns more frequently than liquid water does. Why?

At 100°C, water vapours have more energy than comparable liquid particles. This is because water vapour absorbs more energy than liquid through latent heat of vaporisation.

5. Assume that the latent heats of evaporation for 2 liquids, a and b, are 100 Joule/kg and 350 Joule/kg. Which results in a greater cooling effect?

Since liquid b has a higher latent heat of evaporation, it will acquire more heat from the environment throughout the evaporation process. As a result, a higher cooling effect will be produced.

Updated on: 01-Mar-2024

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