This can be achieved in multiple ways. You can either use a SAP DI documents, an open SQL or use data transfer workbench for this purpose.
You can use a direct SQL write as this is one of straight way to do this. It is also possible to use SAP-DI Documents object to iterate over the Purchase Orders.
One more option is using Data Transfer Workbench (DTW), where you export it to a file and then using DTW. It also provides error handling incase any exception occurs.